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Ozone (O3)

Unlike other pollutants, ozone (O3) is not emitted directly by human activities. O3 in the lower atmosphere is produced by a complicated set of chemical reactions involving oxides of nitrogen (NOx) and volatile organic compounds (VOCs) in the presence of sunlight. O3 is also transported to the ground from the "ozone rich" upper atmosphere by natural weather processes. O3 and its precursors, such as NOx and VOCs, may also be carried from upwind sources such as urban centres and industrial complexes. A major source of VOCs in rural areas is natural emissions from trees and vegetation.

O3 concentrations are generally lower at urban locations than at rural locations. This is due to the destruction of O3 by nitric oxide (NO) that is emitted by vehicles. O3 levels are usually higher during the spring and summer months because of more transport from the upper atmosphere and more sunlight with allows O3 forming chemical reactions to occur more rapidly.

At normal outdoor concentrations, O3 is a colourless, odourless gas. However, O3 does have a characteristic of sharp odour when at very high concentrations, such as that associated with lightning storms.

Objectives
The Objectives for O3 are based on the prevention of adverse effects to human health and vegetation. The ambient air quality Objectives for O3 in Alberta are:

  • 0.082 ppm (parts per million) as a 1-hour average concentration.

The Canada-wide Standard (CWS) benchmark concentration for 8-hour O3 concentrations is 0.065 ppm. The actual achievement statistic for the O3 CWS is based on a complex calculation process that involves using the fourth highest measurement annually, averaged over three consecutive years.

Monitoring Methods
An ultra-violet (UV) light process is used o continuously monitor O3. The sampled air is exposed to UV light, which is absorbed by O3. The amount of UV light absorbed is proportional to the amount of O3 in the sample; that is, the more UV light is absorbed, the greater the amount of O3 in the sample.